import com.spire.doc.Document; 
import com.spire.ms.System.Drawing.Printing.PrinterSettings;
public class PrintWord {
public static void main(String[] args) { 

  //加载Word文档 
  Document document = new Document(); 
  document.loadFromFile("C:\\Users\\Administrator\\Desktop\\DocoumentToPrint.docx"); 

  //创建PrinterSettings对象 
  PrinterSettings printerSettings = new PrinterSettings(); 

  //指定物理打印机名称 
  printerSettings.setPrinterName("\\\\192.168.1.104\\HP LaserJet P1007"); 

  //设置打印份数 
  printerSettings.setCopies((short) 1); 

  //设置打印范围 
  printerSettings.setFromPage(2); 
  printerSettings.setToPage(4); 

  //应用打印设置 
  document.getPrintDocument().setPrinterSettings(printerSettings); 

  //执行打印 
  document.getPrintDocument().print(); 
} 
}

import com.spire.doc.Document; 
import com.spire.ms.System.Drawing.Printing.PrinterSettings;
public class PrintWord {
public static void main(String[] args) { 

  //加载Word文档 
  Document document = new Document(); 
  document.loadFromFile("C:\\Users\\Administrator\\Desktop\\DocumentToPrint.docx"); 

  //创建PrinterSettings对象 
  PrinterSettings printerSettings = new PrinterSettings(); 

  //指定虚拟打印机 
  printerSettings.setPrinterName("Microsoft Print to PDF"); 

  //打印到文档 
  printerSettings.setPrintToFile(true); 

  //指定打印文档的保存路径和名称 
  printerSettings.setPrintFileName("output/PrintToPDF.pdf"); 

  //应用打印设置 
  document.getPrintDocument().setPrinterSettings(printerSettings); 

  //执行打印 
  document.getPrintDocument().print(); 
} 
}